Acid-Catalyzed Reactions of α,β-Unsaturated Aldehydes and Ethyl Diazoacetate.
✍ Scribed by Bryan Branstetter; M. Mahmun Hossain
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 17 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The direct organocatalytic enantioselective epoxidation of α,β‐unsaturated aldehydes with different peroxides is presented. Proline, chiral pyrrolidine derivatives, and amino acid‐derived imidazolidinones catalyze the asymmetric epoxidation of α,β‐unsaturated aldehydes. In particular, p