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Asymmetric Lewis Acid Catalyzed Diels—Alder Reactions of α,β-Unsaturated Ketones and α,β-Unsaturated Acid Chlorides.

✍ Scribed by Joel M. Hawkins; Mitch Nambu; Stefan Loren

Publisher
John Wiley and Sons
Year
2004
Weight
142 KB
Volume
35
Category
Article
ISSN
0931-7597

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Diels-Alder Reactions of α,β-Unsaturated Thioesters and α,β-Unsaturated Selenoesters. -The regio-and exo/endo-selectivity of Diels-Alder reactions of thio-and selenoesters (II) with dienes is investigated. In general, thermal reactions show only low selectivities as expected. The selectivity improv