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Cyclopropylcarbinyl-Type Ring Openings. Reconciling the Chemistry of Neutral Radicals and Radical Anions

โœ Scribed by Stevenson, J. Paige; Jackson, Woodward F.; Tanko, J. M.


Book ID
121506255
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
148 KB
Volume
124
Category
Article
ISSN
0002-7863

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โœ David Crich; Qingwei Yao ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 779 KB

It is demonstrated that nucleotide C4' radicals may be generated from a C4'-thiolester on treatment with tributyldn hydride. When the reaction is conducted in benzene at reflux the (24' radical expels the C3'phosphate group to give a radical cation. This species undergoes deprotonation to an allylic