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Molecular Orbital Calculations of Ring Opening of the Isoelectronic Cyclopropylcarbinyl Radical, Cyclopropoxy Radical, and Cyclopropylaminium Radical Cation Series of Radical Clocks

โœ Scribed by Cooksy, Andrew L.; King, Harry F.; Richardson, William H.

Book ID
127257058
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
288 KB
Volume
68
Category
Article
ISSN
0022-3263

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Ab initio Molecular Orbital Calculations of Electronic Effects on the Kinetics of Cyclopropylcarbinyl Radical Ring Openings. -The heats of reaction and barriers for ring opening of cyclopropylcarbinyl radicals with a vinyl or methoxy substituent at each possible position or a methyl substituent at