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Cyclopropyl participation in the solvolysis of 2-cyclopropylethyl brosylates

โœ Scribed by Dewar, Michael J. S.; Harris, John Milton.

Book ID
126858527
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
520 KB
Volume
92
Category
Article
ISSN
0002-7863

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โœ Joe C. Greever; Donald E. Gwynn ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 195 KB

Numerous studies have shown the P-norbornyl cation to exhibit a remarkable degree of exo-stereospecificity upon nucleophilic substitution. 1 2-4 Some recent work, however, has shown this stereospecificity to be lost upon incorporation of an electron withdrawing substituent located either 01 or S to