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Cyclopropanes. XXVIII. Rearrangement and reactivity of the 1-methyl-2,2-diphenylcyclopropyl radical

✍ Scribed by Walborsky, Harry M.; Chen, Jong-Chen.

Book ID
126842260
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
782 KB
Volume
92
Category
Article
ISSN
0002-7863

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The dimer of 2-methyl-1,1-diphenylpropyl
The dimer of 2-methyl-1,1-diphenylpropyl radicals and its reactivity
✍ Hans-Dieter Beckhaus; JΓΌrgen Schaetzer; Christoph RΓΌchardt πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 221 KB

The title radicals dimerize to an a,p-dimer 1 and not to an cr,a-dimer 2 as previously 8) assumed. The structure of the dimers of t-benzhydryl radicals Ph2CR in general is strongly dependent on the bulkiness of the R group. Benzyl type radicals l can dimerize to form either a,n-dimers 2 or a,p-dime