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Formation of a chiral 1-fluoro-2,2-diphenylcyclopropyl radical in the Barton decarboxylation reaction

โœ Scribed by Gawronska, K.; Gawronski, J.; Walborsky, H. M.

Book ID
126187231
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
681 KB
Volume
56
Category
Article
ISSN
0022-3263

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Results obtained from the photolysis of ketene with acetylene strongly support the formation of C,H, radicals in the title reaction. Stationary state studies are interpreted in terms of the reaction C,H: 5 C,H, + H with a rate constant (log8 s '1 which is compared to RRKM predictions. In pulsed lase