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The dimer of 2-methyl-1,1-diphenylpropyl radicals and its reactivity

✍ Scribed by Hans-Dieter Beckhaus; Jürgen Schaetzer; Christoph Rüchardt

Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
221 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis

The title radicals dimerize to an a,p-dimer 1 and not to an cr,a-dimer 2 as previously 8) assumed. The structure of the dimers of t-benzhydryl radicals Ph2CR in general is strongly dependent on the bulkiness of the R group.

Benzyl type radicals l can dimerize to form either a,n-dimers 2 or a,p-dimers 22). The latter dimerisation process seems to be favoured ZZ

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