Cyclopropane as a neighboring group in t
โ
I.M. Takakis; Yorke E. Rhodes
๐
Article
๐
1978
๐
Elsevier Science
๐
French
โ 268 KB
The propensity of cyclopropane to stabilize remote incipient carbocationic centers has been dmmstrated in the solvolyses of gecmetrically constrained substrates'. In contrast, cyclopropane-cation interaction (kAcc H 3 5) is weak cmpared to nucleophilic solvent assistance