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Cyclopropane as a neighboring group in solvolyses of 2-(1-methylcycloprohyl)ethyl arenesulfonates

โœ Scribed by Yorke E. Rhodes; I.M. Takakis; Paul E. Schueler; Robert A. Weiss


Book ID
104245830
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
263 KB
Volume
19
Category
Article
ISSN
0040-4039

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Cyclopropane as a neighboring group in t
โœ I.M. Takakis; Yorke E. Rhodes ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 268 KB

The propensity of cyclopropane to stabilize remote incipient carbocationic centers has been dmmstrated in the solvolyses of gecmetrically constrained substrates'. In contrast, cyclopropane-cation interaction (kAcc H 3 5) is weak cmpared to nucleophilic solvent assistance