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Formation of 1,2-O-(1,2-ethanediyl)-β-d-mannopyranose in a neighboring-group participation reaction of 2-O-(2-hydroxyethyl)-d-mannose

✍ Scribed by Miroslaw J. Tomaszewski; Kevin R. Holme; Arthur S. Perlin


Book ID
107726098
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
580 KB
Volume
217
Category
Article
ISSN
0008-6215

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Formation, and stereochemistry, of 1,2-O
✍ Dae-Sil Lee; Arthur S. Perlin 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 883 KB

In the hydrolysis of O-(2-hydroxypropyl)cellulose, residues of D-gh.ICOSe substituted with a single O-(2-hydroxypropyl) substituent at O-2 (irrespective of the pattern of additional substitution at O-3 or O-6) form 1,2-0-(1-methyl-1,2ethanediyl)-a-D-glucose acetals. Based on the characteristics of 2