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Cyclopropane as a neighboring group in trifluoroethanolysis of 2-cyclopropylethyl tosylate

✍ Scribed by I.M. Takakis; Yorke E. Rhodes

Book ID: 104245829
Publisher: Elsevier Science
Year: 1978
Tongue: French
Weight: 268 KB
Volume: 19
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)94804-x

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✦ Synopsis

The propensity of cyclopropane to stabilize remote incipient carbocationic centers has been dmmstrated in the solvolyses of gecmetrically constrained substrates'. In contrast, cyclopropane-cation interaction (kAcc H 3 5) is weak cmpared to nucleophilic solvent assistance

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