3-O-Benzyl-5-deoxy-1,2-O-isopropylidene-a-D-xylo-hexadialdo-1,4-furanose (2) upon treatment with Lirv(TMS)2 at -500 furnished the e&ate which reacted with methyl 2,3,4-tri-Obenzyl-a-D-glucopyranoside-6-ulose (5) to afford two eythro aldols 3 and 4 in 6:l ratio and 43% yield. 5R;6R Confguration was a
โฆ LIBER โฆ
Cyclopentenone synthesis via aldol condensation. Synthesis of a key prostaglandin intermediate
โ Scribed by Robert A. Ellison; Elvin R. Lukenbach; Chung-wei Chiu
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 173 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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