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Cyclopentanoid allysilanes in synthesis: Generation via intramolecular ene reaction of activated 1,6-dienes and application to the synthesis of functionalized diquinanes

✍ Scribed by T.K. Sarkar; S.K. Ghosh; P.S.V. Subba Rao; T.K. Satapathi

Book ID: 104228679
Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 249 KB
Volume: 31
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)97422-7

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✦ Synopsis

A new general route to cis-1,2_disubstituted cyclopentanoid allylsilanes useful in di-and triquinane synthesis isdescribed based on intramolecular ene reaction of activated 1,6-dienes featuring a homoallylsilane unit as the ene donor.

Allylsilanes are versatile compounds with well documented utility in organic synthesis.

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