5-Membered heterocyclic allylsilanes in synthesis: Generation via aza-ene reaction and application to the synthesis of a bicyclic 1,2-dinitrogen analogue of naturally occurring pyrrolizidines

✍ Scribed by Tarun K. Sarkar; Pulak Gangopadhyay; Tushar K. Satapathi

• Publisher: Elsevier Science
• Year: 1999
• Tongue: French
• Weight: 141 KB
• Volume: 40
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(98)02363-6

✦ Synopsis

A cyclic hydrazide containing an allylsilane functionality obtainable by an aza-ene reaction provides ready access to a bicyclic 1, 2-dinitrogen compound related to naturally occurring pyrrelizidines.