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Stereochemical Control over Three Contiguous Stereogenic Centers in the Intramolecular Ene Reaction of Activated 1,6-Dienes. Application to the Synthesis of (±)-Methyl Cucurbate and (±)-Methyl Epijasmonate

✍ Scribed by Sarkar, Tarun K.; Ghorai, Binay K.; Nandy, Sandip K.; Mukherjee, Bireswar; Banerji, Asoke


Book ID
126131332
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
142 KB
Volume
62
Category
Article
ISSN
0022-3263

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Cyclopentanoid allysilanes in synthesis:
✍ T.K. Sarkar; S.K. Ghosh; P.S.V. Subba Rao; T.K. Satapathi 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 249 KB

A new general route to cis-1,2\_disubstituted cyclopentanoid allylsilanes useful in di-and triquinane synthesis isdescribed based on intramolecular ene reaction of activated 1,6-dienes featuring a homoallylsilane unit as the ene donor. Allylsilanes are versatile compounds with well documented utili