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Cyclopentadienyl N-heterocyclic carbene–nickel complexes as efficient pre-catalysts for the hydrosilylation of imines

✍ Scribed by Bheeter, Linus P.; Henrion, Mickaël; Chetcuti, Michael J.; Darcel, Christophe; Ritleng, Vincent; Sortais, Jean-Baptiste

Book ID
121081070
Publisher
The Royal Society of Chemistry
Year
2013
Tongue
English
Weight
701 KB
Volume
3
Category
Article
ISSN
2044-4753

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✍ Fan Jiang; David Bézier; Jean-Baptiste Sortais; Christophe Darcel 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 185 KB 👁 2 views

## Abstract Hydrosilylation with well defined piano‐stool iron(II) complexes bearing both N‐heterocyclic carbene and cyclopentadienyl ligands was accomplished with both aldehydes and ketones. Typically, the reduction of aldehydes exhibited good activities (full reduction at 30 °C in 3 h), whereas f