Cyclopentadienic compounds as intermediates in the thermal degradation of phenols. Kinetics of the thermal decomposition of cyclopentadiene
β Scribed by R. Spielmann; C. A. Cramers
- Book ID
- 112730121
- Publisher
- Springer
- Year
- 1972
- Tongue
- English
- Weight
- 432 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0009-5893
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## Abstract Thermal decomposition of cyclopentadiene to __c__βC~5~H~5~ (cyclopentadienyl radical) + H (1) and the reverse bimolecular reaction (β1) are studied quantumβchemically at the G2M level of theory. The dissociation pathway has been mapped out following the minimum energy path on the potent
Kinetics of the thermal degradation of the phenolic acids gallic and protocatechuic acid in 0,05 M citrate buffer at pH 3,4 and 5 and temperature 101, 11 I and 121 "C has been investigated. It has been established that the degradation is a first order reaction. The rate constants, half life period T