Kinetics of the thermal isomerization of 2-methyl-1,3-cyclopentadiene
โ Scribed by V. A. Mironov; A. A. Akhrem
- Book ID
- 112421667
- Publisher
- Springer
- Year
- 1972
- Tongue
- English
- Weight
- 175 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1573-9171
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B 371 1 -Ethynyl-2,2,3,3-tetramethylcyclopropane (9) has been prepared and subjected to gas phase pyrolysis. Above 200ยฐC the hydrocarbon rearranges to 4,4,5-trimethyl-I ,2,5-hexatriene (10) and 5,6dimethyl-5-hepten-I-yne (11). Whereas the allene is produced directly from 9 by a 1,Shydrogen shift, th
## Abstract Reaction rates for the structural isomerization of 1,1,2,2โtetramethylcyclopropane to 2,4โdimethylโ2โpentene have been measured over a wide temperature range, 672โ750 K in a static reactor and 1000โ1120 K in a singleโpulse shock tube. The combined data from the two temperature regions g
## Abstract The Arrhenius parameters for the gas phase, unimolecular structural isomerizations of 1,1,2โtrimethylcyclopropane to three isomeric methylpentenes and two dimethylbutenes have been determined over a wide range of temperatures, 688โ1124 K, using both static and shock tube reactors. For t