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Cyclopenta[b]indoles. Part 1. Synthesis of cyclopenta[b]indoles by formal [3 + 2] addition of indolylmethyl cations to alkenes

✍ Scribed by Harrison, Carrie-Ann; Leineweber, Ralf; Moody, Christopher J.; Williams, Jonathan M. J.


Book ID
120275858
Publisher
Royal Society of Chemistry
Year
1995
Weight
502 KB
Volume
9
Category
Article
ISSN
1472-7781

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Synthesis of Cyclopenta[b]indol-1-ones a
✍ Ulrik S. Sørensen; Esteban Pombo-Villar 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 German ⚖ 119 KB

## Abstract An efficient synthetic route towards __N__‐methylated or nonmethylated 3,4‐dihydrocyclopent[__b__]indol‐1(2__H__)‐ones (**3**) and 1,2,3,9‐tetrahydrocarbazol‐4(4__H__)‐one (**10**) was elaborated, based on Pd‐catalyzed intramolecular __Heck__ reaction. The chemoselectivity of the cycliz