## Abstract An efficient synthetic route towards __N__‐methylated or nonmethylated 3,4‐dihydrocyclopent[__b__]indol‐1(2__H__)‐ones (**3**) and 1,2,3,9‐tetrahydrocarbazol‐4(4__H__)‐one (**10**) was elaborated, based on Pd‐catalyzed intramolecular __Heck__ reaction. The chemoselectivity of the cycliz
Synthesis of Cyclopenta[b]indol-1-ones and Carbazol-4-ones from N-(2-Halophenyl)-Substituted Enaminones by Intramolecular Heck Reaction.
✍ Scribed by Ulrik S. Soerensen; Esteban Pombo-Villar
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 125 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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Abstract
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## Abstract magnified image The photostimulated reaction of enolate anions of cyclic aromatic ketones such as substituted indan‐1‐ones and 3,4‐dihydro‐2__H__‐naphthalen‐1‐one with __o__‐iodoaniline in DMSO affords 1‐, 2‐, 3‐, and 4‐methoxy‐5,10‐dihydroindeno[1,2‐__b__]indoles (34‐40%), 1,2‐, 1,4‐,
## Abstract For Abstract see ChemInform Abstract in Full Text.