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Cyclooligomerization of 1,3-butadiene by nickel π-complexes

✍ Scribed by Tajima, Yoshio ;Kunioka, Estuo


Publisher
Wiley (John Wiley & Sons)
Year
1967
Tongue
English
Weight
136 KB
Volume
5
Category
Article
ISSN
0449-2986

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## Abstract Various π‐allylic nickel complexes were synthesized by reacting bis(1,5‐cyclooctadiene)‐nickel with an allylic ester of trifluoroacetic acid. A study of the stereospecific polymerization of 1,3‐butadiene initiated by these catalysts showed the strong influence of the initial substitutio