PMR study of BIS-(π-crotyl nickel iodide) reaction with 1,3 - butadiene
✍ Scribed by Lobach, M. I. ;Kormer, V. A. ;Tsereteli, I. Yu. ;Kondratenkov, G. P. ;Babitskii, B. D. ;Klepikova, V. I.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1971
- Tongue
- English
- Weight
- 212 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0449-2986
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By 13C NMR spectroscopy, the structures of (C4DTNil)2 adducts with isoprene, 2-ethyl-, 2-isopropyl-and 2-tert. butylbutadienes have been investigated. The nature of the 2-alkyl substituent in the anti-and syn-l.2-disubstituted rc-allylic complexes influences the character of electron charge densitie
+ 2) Cycloaddition / Zwitterion formation / Ketene aminal l,l-Bis(dimethylamino)-1,3-butadiene (1) as a strong donor diene = 0.03 V vs. SCE, 1st IP, = 6.94 eV) is treated with acrylonitrile, dimethyl dicyanofumarate, and tetracyanoethylene. Cycloaddition with acrylonitrile is slow and requires eleva