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PMR structural study of trifluoroacetato-h3-allyl nickel complexes in butadiene 1,4-polymerization

✍ Scribed by R. Warin; Ph. Teyssié; P. Bourdaudurq; F. Dawans


Publisher
Wiley (John Wiley & Sons)
Year
1973
Tongue
English
Weight
279 KB
Volume
11
Category
Article
ISSN
0887-6258

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## Abstract Compounds [{Au(pz)(PPh~3~)}~2~] (pz=3,5‐disubstituted pyrazolato; R=BuOC~6~H~4~ (bp), 1; R=C~8~H~17~OC~6~H~4~ (op), 2; R=C~6~H~13~OC~6~H~4~ (hp), 3) were easily obtained by reaction of [Au(NO~3~)(PPh~3~)] and the corresponding pyrazolato ligand. They exhibit similar NMR patterns, their