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Cycloaddition Reactions of Imines with 3-Thiosuccinic Anhydrides: Synthesis of the Tricyclic Core of Martinellic Acid

โœ Scribed by Ng, Pui Yee; Masse, Craig E.; Shaw, Jared T.


Book ID
127188572
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
750 KB
Volume
8
Category
Article
ISSN
1523-7060

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๐Ÿ“œ SIMILAR VOLUMES


Cycloaddition Reactions of Imines with 3
โœ Pui Yee Ng; Craig E. Masse; Jared T. Shaw ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› John Wiley and Sons โš– 26 KB

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Synthesis of the tricyclic triamine core
โœ Barry B. Snider; Yong Ahn; Bruce M. Foxman ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 247 KB

The tricyclic triamine core 27 of martinellic acid (2) has been prepared stereospecifically in eight steps from 2-hydroxymethylaniline in 11% overall yield. The key steps are the addition of 2hydroxymethylaniline to vinylcyclopropane 14 to prepare cycloaddition precursor 19 in only two steps and an