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Cycloaddition reactions of carbonyl ylides to [60] fullerene: Synthesis of novel C60 derivatives

โœ Scribed by Vijay Nair; D. Sethumadhavan; K.C. Sheela; Guenter K. Eigendorf


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
171 KB
Volume
40
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


1,3-Dipolar cycloaddition reactions of carbonyl ylides with [60] fullerene afforded novel cycioadducts.


๐Ÿ“œ SIMILAR VOLUMES


The first 1,3-dipolar cycloaddition reac
โœ Hiroshi Ishida; Masatomi Ohno ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 245 KB

A thiocarbonyl ylide generated by sila-Pummerer rearrangement of bis(trimethylsilylmethyl) sulfoxide reacted with C6o to give a tetrahydrothiophene-fused C6o derivative. The cycloadduct was readily oxidized with mCPBA to give the corresponding sulfoxide and sulfone derivatives, which are useful for