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1,3-Dipolar cycloaddition of pyrazolidinium ylides to C60 fullerene

โœ Scribed by Wolfram Duczek; Hans-Joachim Niclas


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
108 KB
Volume
36
Category
Article
ISSN
0040-4039

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A thiocarbonyl ylide generated by sila-Pummerer rearrangement of bis(trimethylsilylmethyl) sulfoxide reacted with C6o to give a tetrahydrothiophene-fused C6o derivative. The cycloadduct was readily oxidized with mCPBA to give the corresponding sulfoxide and sulfone derivatives, which are useful for