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The first 1,3-dipolar cycloaddition reaction of [60]fullerene with thiocarbonyl ylide

✍ Scribed by Hiroshi Ishida; Masatomi Ohno

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
245 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

A thiocarbonyl ylide generated by sila-Pummerer rearrangement of bis(trimethylsilylmethyl) sulfoxide reacted with C6o to give a tetrahydrothiophene-fused C6o derivative. The cycloadduct was readily oxidized with mCPBA to give the corresponding sulfoxide and sulfone derivatives, which are useful for further functionalization.

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