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Cycloaddition reaction of heterocumulenes and ester enolates: A novel synthesis of 4-alkylidene-azetidin-2-ones.

โœ Scribed by Arturo Battaglia; Gianfranco Cainelli; Daria Giacomini; Giorgio Martelli; Mauro Panunzio


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
225 KB
Volume
28
Category
Article
ISSN
0040-4039

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โœ Gianfranco Cainelli; Daria Giacomini; Paola Galletti; Arianna Quintavalla ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 215 KB ๐Ÿ‘ 1 views

## Abstract We report the synthesis of a class of 4โ€(2โ€oxoethylidene)azetidinโ€2โ€ones by a novel Lewis acid mediated reaction of acyldiazo compounds with 4โ€acetoxyazetidinโ€2โ€ones. Using this approach, Cโ€3โ€and Cโ€4โ€substituted 4โ€alkylideneazetidinโ€2โ€ones were obtained depending on the choice of starti