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Cycloaddition of nitrile oxides to [60]fullerene

✍ Scribed by Ros, Tatiana Da; Prato, Maurizio; Novello, Fabiola; Maggini, Michele; Amici, Marco De; Micheli, Carlo De

Book ID
121526932
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
42 KB
Volume
1
Category
Article
ISSN
1359-7345

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Cycloaddition of Nitrile Oxides to (60)Fullerene. -Addition of nitrile oxides to (60)fullerene gives fullerene-fused isoxazolines (cf. (III)), which can regenerate the (60)fullerene under relatively mild conditions. -(DA

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## Abstract Cycloaddition of nitrile oxides to [60]fullerene led to [60]fullereno[1,2‐__d__]isoxazole derivatives 1b–d. [60]Fullereno[1,2‐__d__]isoxazole (1a) is the corresponding cycloadduct with fulminic acid. X‐ray structure analyses of compound 1b and 1e were determined.