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Twofold cycloaddition of[60]fullerene to a bifunctional nitrile oxide

✍ Scribed by Hermann Irngatinger; Anton Weber

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
165 KB
Volume
37
Category
Article
ISSN
0040-4039

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Cycloaddition of Nitrile Oxides to (60)Fullerene. -Addition of nitrile oxides to (60)fullerene gives fullerene-fused isoxazolines (cf. (III)), which can regenerate the (60)fullerene under relatively mild conditions. -(DA

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## Abstract Cycloaddition of nitrile oxides to [60]fullerene led to [60]fullereno[1,2‐__d__]isoxazole derivatives 1b–d. [60]Fullereno[1,2‐__d__]isoxazole (1a) is the corresponding cycloadduct with fulminic acid. X‐ray structure analyses of compound 1b and 1e were determined.