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Cycloaddition of [60]fullerene to stable benzenedicarbonitrile oxides

✍ Scribed by V. N. Knyazev; N. M. Przheval'skii; G. P. Tokmakov; A. G. Buyanovskaya

Publisher
Springer
Year
1999
Tongue
English
Weight
141 KB
Volume
48
Category
Article
ISSN
1573-9171

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Cycloaddition of Nitrile Oxides to (60)Fullerene. -Addition of nitrile oxides to (60)fullerene gives fullerene-fused isoxazolines (cf. (III)), which can regenerate the (60)fullerene under relatively mild conditions. -(DA

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## Abstract Cycloaddition of nitrile oxides to [60]fullerene led to [60]fullereno[1,2‐__d__]isoxazole derivatives 1b–d. [60]Fullereno[1,2‐__d__]isoxazole (1a) is the corresponding cycloadduct with fulminic acid. X‐ray structure analyses of compound 1b and 1e were determined.