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Cycloaddition and copolymerization of methyl tricyanoethylenecarboxylate with electron-rich olefins

✍ Scribed by Hall, H. K.; Padias, Anne Buyle; Way, Tun Fun; Bergami, Bridgette

Book ID
126913374
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
479 KB
Volume
52
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Extended dipolar cycloaddition reactions
Extended dipolar cycloaddition reactions of 3-diazopyrazoles with electron rich olefins
✍ Albert Padwa; Tsutomu Kumagai πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 190 KB

## 3-Diazo-4-methyl-5-phenylpyrazole readily adds to electron rich olefins to give 1,7-cycloadducts, The mechanism of the reaction consists of an initial 1,3-dipolar cycloaddition followed by a subsequent rearrangement.