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Cycloaddition and polymerization reactions of methyl .alpha.-cyanoacrylate with electron-rich olefins

✍ Scribed by Rasoul, H. A. A.; Hall, H. K.


Book ID
126193297
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
474 KB
Volume
47
Category
Article
ISSN
0022-3263

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Extended dipolar cycloaddition reactions
✍ Albert Padwa; Tsutomu Kumagai πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 190 KB

## 3-Diazo-4-methyl-5-phenylpyrazole readily adds to electron rich olefins to give 1,7-cycloadducts, The mechanism of the reaction consists of an initial 1,3-dipolar cycloaddition followed by a subsequent rearrangement.