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Competition between cycloaddition and spontaneous copolymerization of 4-methyl-1,3-pentadiene with electrophilic olefins

โœ Scribed by Mikhael, Michael G.; Padias, Anne Buyle; Hall, H. K.


Book ID
127263273
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
590 KB
Volume
26
Category
Article
ISSN
0024-9297

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Reaction of bicyclo[3.2.1]octadiene with
โœ Waldemar Adam; Ottorino De Lucchi ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 226 KB

The nonconjugated bicyclo[3.2.l]octa-2,6-diene (1) affords with 4-methyl-1,2,4-triazolin-3,5-dione (MTAD) the homo-cycloadduct (2) product and the rearranged urazoles ( 2) and ( 2) through dipolar cycloaddition, while ene-reaction and (2+2)-cycloaddition are not observed. Bicyclo[3.2.l]octa-2,6-die