On the biogenetic type synthesis of polycyclic terpenoid from acyclic precursor, there are several reports\* in which the initiation of ring closure is caused by i.) protonation to the terminal Couble bond, or ii) opening of the
Cyclization of polyenes: XII. Direct brominative ring closure of polyenes
β Scribed by Tadahiro Kato; Isao Ichinose; Satoru Kumazawa; Yoshio Kitahara
- Book ID
- 103481615
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 398 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0045-2068
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## Abstract A variety of epoxy polyene terpenes cyclize readily by confinement within zeolite NaY to form primarily products of monocyclization. The monocyclization pathway is highly predominant, irrespectively of the side chain of the epoxy terpene, while the monocyclic products possess regioselec