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Cyclization of polyenes XIV. Easy synthesis of A/B ring system of higher terpenoids

✍ Scribed by Tadahiro Kato; Satoru Kuniazawa; Chizuko Kabuto; Tsugio Honda; Yoshio Kitahara


Book ID
104215020
Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
189 KB
Volume
16
Category
Article
ISSN
0040-4039

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Enantioselective synthesis of the nagila
✍ Steven D. Burke; Sharon M.S. Strickland; Helen M. Organ; Louis A. Silks III πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 238 KB

The functionalized tricyclic nagilactone precursor 19 was synthesized by a route featuring a vinylsilane terminated/1,3-dioxane acetal initiated bicyclization. Relative and absolute stereochemical control were achieved via the optically active pentenolide template 14.