Cyclization of 2-(3-butenyl)bromobenzene via the aryllithium derivative
β Scribed by Ross, Gerald A.; Koppang, Miles D.; Bartak, Duane E.; Woolsey, Neil F.
- Book ID
- 126837137
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 279 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Cyclization of 4-(3'-butenyl)azetidin-2-one, 2 initiated by electrophilic reagents such as 12, Hg(OAc)2 results in the formation of bicyclic B-lactams having the carbopenam ring skeleton. Reaction of gwith Br2 results in simple addition of Br2 to the double bond, while PhSBr gives a mixture of cycli
## Abstract magnified image A novel method for the preparation of 2,3βdihydroimidazo[2,1β__b__]thiazole **9** by iodination and subsequent cyclization of the easily available __N__βallylimidazolineβ2βthiones **5**, is described. Selected transformations of the iodomethyl derivatives **9**, leading