Cyclization rate measurements were carried out on polystyrene chains of different molecular weights and labelled at both ends with I-pyrenyl groups, using as solvents cyclopentane (a thetasolvent), acetone (a poor solvent), and their mixtures. These mixtures exhibit a cosolvency effect for polystyre
β¦ LIBER β¦
Cyclization dynamics of polymers. 2. Dynamics and thermodynamics of end-to-end cyclization of polystyrene in a .THETA. solvent
β Scribed by Redpath, A. E. C.; Winnik, Mitchell A.
- Book ID
- 126925871
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 392 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The dynamics of the concentration fluctuations in endβgrafted polystyrene brushes in a theta solvent (cyclohexane) are probed by evanescent wave dynamic light scattering at different wavevectors __q__ and temperatures. When the solvent quality changes from marginal to poor, the relaxati
THE DYNAMICS OF POLYMER CYCLIZATION 3. E
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