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Cyclization dynamics of polymers. 18. Capture radius effects in the end-to-end cyclization rate of polymers

✍ Scribed by Sinclair, Andrew M.; Winnik, Mitchell A.; Beinert, Gerard


Book ID
127012228
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
388 KB
Volume
107
Category
Article
ISSN
0002-7863

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Cyclization dynamics of polymers, 26. En
✍ Martinho, JosΓ© M. G. ;Martinho, Maria Helena ;Winnik, Mitchell A. ;Beinert, GΓ©ra πŸ“‚ Article πŸ“… 1989 πŸ› Wiley (John Wiley & Sons) βš– 520 KB

Cyclization rate measurements were carried out on polystyrene chains of different molecular weights and labelled at both ends with I-pyrenyl groups, using as solvents cyclopentane (a thetasolvent), acetone (a poor solvent), and their mixtures. These mixtures exhibit a cosolvency effect for polystyre