Cyclic alkyl radical isomerization: A correction to the literature
β Scribed by Robin Walsh
- Publisher
- John Wiley and Sons
- Year
- 1970
- Tongue
- English
- Weight
- 188 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0538-8066
No coin nor oath required. For personal study only.
β¦ Synopsis
Kerr and coworkers refer to A. S. Gordon, Pure Appl. Chem., 15, 441 (1962), but the data is the same as that in [lc], Bibliography.
π SIMILAR VOLUMES
## Abstract The addition of cyclohexane to alkylmaleic anhydrides 1aβf via cyclic radicals 2aβf gave a mixture of (__Z__)β and (__E__)β2,3βdialkylsuccinic anhydrides 3aβf. The stereoselectivity of the hydrogen transfer from cyclohexane to radicals 2aβd was measured in the temperature range of 200β2
X-ray structure data: triclinic, spacegroup Pi, (I = 12.167(2) A, 6 = 12.921(4) A, c = 15.394(4) .&, a = 314.41(2)". = 97.641(15)", y = 102,17(2)", V = 2087.4 A,, Z = 1, data collected 4.0' 5 28 5 45.0". 4179 unique reflections with F > 6.0u(F), R = 0.046. R, = 0.059. Further details of the crystal