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Isoselective Relationship for the Stereoselectivity of the Transfer of Hydrogen Atoms to Cyclic Alkyl Radicals

✍ Scribed by Prof. Dr. Bernd Giese; Dr. Hassan Farshchi; Dr. Jörg Hartmanns; Priv.-Doz. Dr. Jürgen O. Metzger

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
269 KB
Volume
30
Category
Article
ISSN
0044-8249

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✦ Synopsis

X-ray structure data: triclinic, spacegroup Pi, (I = 12.167(2) A, 6 = 12.921(4) A, c = 15.394(4) .&, a = 314.41(2)". = 97.641(15)", y = 102,17(2)", V = 2087.4 A,, Z = 1, data collected 4.0' 5 28 5 45.0". 4179 unique reflections with F > 6.0u(F), R = 0.046. R, = 0.059. Further details of the crystal structure investigations are available on request from the Director of the Cambridge Crystallographic Data Center, University Chemical Laboratory, Lensfield Road, GB-Cambridge CB2 IEW (U. K.), on quoting the complete journal citation. Satisfactory elemental analysis for Fe,CI,OZ,N,C,,H,,(3~CH~Cl,). Mossbauer hyperfine parameters for two doublets in area ratio of 1 :2 (values relative to iron foil): 300 K: 6 [0.406(6), 0.383(3) mm/s]; AEQ

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