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Cyanobacterium-catalyzed asymmetric reduction of ketones

✍ Scribed by Kaoru Nakamura; Rio Yamanaka; Keiko Tohi; Hiroki Hamada


Book ID
108379933
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
110 KB
Volume
41
Category
Article
ISSN
0040-4039

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## Abstract The equimolar mixture of __N__‐(hydroxyalkyl)pyrazoles and borane formed boric ester complex, in which the remaining borane was stabilized by the adjacent nitrogen of thr pyrazole ring. The borane complex derived from the chiral pyrazoles such as 3‐phenyl‐__l__‐menthopyrazole reduced __