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Asymmetric reduction of a ketone by knockout mutants of a cyanobacterium

โœ Scribed by Tetsuo Takemura; Kaori Akiyama; Nobuaki Umeno; Yukiko Tamai; Hisataka Ohta; Kaoru Nakamura


Book ID
113804490
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
229 KB
Volume
60
Category
Article
ISSN
1381-1177

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Light-mediated regulation of asymmetric
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The stereochemical course of the asymmetric reduction of ketones by a photosynthetic microbe is largely regulated by light. Thus, we find that the enantioselectivity of the reduction of a,a-difluoroacetophenone with Synechococcus elongatus PCC 7942 increases as a result of illumination with fluoresc