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Cyano-sugars. Part 4. Hypochlorite oxidation of branched-chain nitro-sugars and conversion of the products into branched-chain cyano-sugars

โœ Scribed by Hall, Richard H.; Jordaan, Amor; Malherbe, Maria

Book ID
111692363
Publisher
Royal Society of Chemistry
Year
1980
Weight
451 KB
Volume
0
Category
Article
ISSN
1472-7781

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Formyl-branched deoxy-sugars (Type B)2 have been accessible by two main routas. Ring contraction3 of a suitable aminopyrancside with nitrous acid gave C-form+deoxyfuranosides. Nucleophilic scission of sugar epoxides with either unsaturated organs-lithium reagants4, or with 2\_lithio-1,3dithiane5, ga