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Synthesis of branched-chain nitro and amino sugars via the nitromethane synthesis

โœ Scribed by Alex Rosenthal; Ong Khong-Seng

Book ID
104239918
Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
153 KB
Volume
10
Category
Article
ISSN
0040-4039

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Synthesis of novel branched-chain amino
Synthesis of novel branched-chain amino sugars: methyl l-sibirosaminide and N-acylkansosamine
โœ Juji Yoshimura; Amjad Aqeel; Ken-Ichi Sato; Rhiddi Bir Singh; Hironobu Hashimoto ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 720 KB

Methyl L-sibirosaminide and N-acylkansosamine were synthesized via the same intermediate, methyl 4-amino-4,6-dideoxy-2,3-O-isopropylidene-3-C-methyl-cY+mannopyranoside ( 7), from L-rhamnose in 7 and 10 steps, respectively. Conversion of 7 into the title compounds was performed by N-methylation or N-