Cu(I)-Catalyzed Regioselective anti-Carbometallation of Secondary Terminal Propargylic Alcohols.
β Scribed by Zhan Lu; Shengming Ma
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 35 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract We have determined that hydrogenated cationic Rh(I)/bisphosphane complexes are highly active catalysts for the isomerization of secondary propargylic alcohols to Ξ±,Ξ²βenones. A kinetic resolution of secondary propargylic alcohols proceeded with moderate selectivity with [Rh((__R__)βBINAP
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