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Cu(I)-Catalyzed Regioselective anti-Carbometallation of Secondary Terminal Propargylic Alcohols.

✍ Scribed by Zhan Lu; Shengming Ma


Publisher
John Wiley and Sons
Year
2006
Weight
35 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract We have determined that hydrogenated cationic Rh(I)/bisphosphane complexes are highly active catalysts for the isomerization of secondary propargylic alcohols to Ξ±,β‐enones. A kinetic resolution of secondary propargylic alcohols proceeded with moderate selectivity with [Rh((__R__)‐BINAP