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Cationic Rhodium(I)/Bisphosphane Complex-Catalyzed Isomerization of Secondary Propargylic Alcohols to α,β-Enones.

✍ Scribed by Ken Tanaka; Takeaki Shoji; Masao Hirano

Publisher: John Wiley and Sons
Year: 2007
Weight: 47 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200738068

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Cationic Rhodium(I)/Bisphosphane Complex

Cationic Rhodium(I)/Bisphosphane Complex-Catalyzed Isomerization of Secondary Propargylic Alcohols to α,β-Enones

✍ Ken Tanaka; Takeaki Shoji; Masao Hirano 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 270 KB

## Abstract We have determined that hydrogenated cationic Rh(I)/bisphosphane complexes are highly active catalysts for the isomerization of secondary propargylic alcohols to α,β‐enones. A kinetic resolution of secondary propargylic alcohols proceeded with moderate selectivity with [Rh((__R__)‐BINAP

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## Abstract For Abstract see ChemInform Abstract in Full Text.