✦ LIBER ✦

Cationic Rhodium(I)/BINAP Complex-Catalyzed Isomerization of Secondary Propargylic Alcohols to α,β-Enones.

✍ Scribed by Ken Tanaka; Takeaki Shoji

Publisher: John Wiley and Sons
Year: 2005
Weight: 27 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200545072

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

📜 SIMILAR VOLUMES

Cationic Rhodium(I)/Bisphosphane Complex

Cationic Rhodium(I)/Bisphosphane Complex-Catalyzed Isomerization of Secondary Propargylic Alcohols to α,β-Enones.

✍ Ken Tanaka; Takeaki Shoji; Masao Hirano 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 47 KB

Cationic Rhodium(I)/Bisphosphane Complex

Cationic Rhodium(I)/Bisphosphane Complex-Catalyzed Isomerization of Secondary Propargylic Alcohols to α,β-Enones

✍ Ken Tanaka; Takeaki Shoji; Masao Hirano 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 270 KB

## Abstract We have determined that hydrogenated cationic Rh(I)/bisphosphane complexes are highly active catalysts for the isomerization of secondary propargylic alcohols to α,β‐enones. A kinetic resolution of secondary propargylic alcohols proceeded with moderate selectivity with [Rh((__R__)‐BINAP