Crystallographic report: Dichloro(β-methoxycarbonylethyl)tin(IV) isopropylxanthate
✍ Scribed by Laijin Tian; Liping Zhang; Xicheng Liu; Zhengyu Zhou
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 69 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.787
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✦ Synopsis
The Sn atom in CH 3 OCOCH 2 CH 2 SnCl 2 [S 2 COCH(CH 3 ) 2 ] adopts a distorted octahedral geometry via the bidentate xanthate ligand and intramolecular carbonyl coordination.
📜 SIMILAR VOLUMES
The centrosymmetric structure of (o-C 6 H 4 CH 2 ) 3 SnS 2 CN(CH 2 CH 2 ) 2 NCS 2 Sn(CH 2 C 6 H 4 -o) 3 features chelating dithiocarbamate ligands, so that a trigonal bipyramidal C 3 S 2 coordination geometry for tin results.
## Abstract The crystal structure of complex [Ph~2~Sn(Hpir)~2~ ·CH~3~CN] shows for the first time chelation to a metal atom of piroxicam through the keto‐enolate oxygen atoms. Copyright © 2004 John Wiley & Sons, Ltd.