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Crystallographic report: Diphenylbis(Hpiroxicam)tin(IV), [Ph2Sn(Hpir)2]

✍ Scribed by Dimitra Kovala-Demertzi; Aglaia Koutsodimou; Angeliki Galani; Sotiris K. Hadjikakou; Mavroudis A. Demertzis; Marianna Xanthopoulou; John R. Miller; Christopher S. Frampton

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
96 KB
Volume
18
Category
Article
ISSN
0268-2605

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✦ Synopsis

Abstract

The crystal structure of complex [Ph~2~Sn(Hpir)~2~ ·CH~3~CN] shows for the first time chelation to a metal atom of piroxicam through the keto‐enolate oxygen atoms. Copyright © 2004 John Wiley & Sons, Ltd.

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## Abstract Each tin atom of the title compound is five‐coordinate, defined by 2C, 2Cl and 1O atoms, and shows a distorted square pyramidal configuration stabilized by intramolecular Sn· · ·O or Sn· · ·Cl interactions. Both nitrate anions coordinate the tin atoms in a monodentate mode. Copyright ©